10月19日薛小松博士学术报告
发布时间: 2020-10-15 浏览次数: 10
 

报告题目:Physical Organofluorine Chemistry: Our Journey toward Predicting the Unpredictable

报告人:南开大学薛小松博士生导师

报告时间:20201019日下午15:10-16:10

报告地点:生化学院7幢二楼会议室

报告人简介薛小松,2007年获北京石油化工学院学士学位(导师林世静教授);2010年获南开大学硕士学位(导师于奡教授);2013年获南开大学博士学位(导师程津培院士)。2017年至2020年,美国University of California, Los Angeles (UCLA)访问学者、研究助理科学家(导师:K. N. Houk教授)。自2013年留校参加工作以来,在氟化学领域开展了较为系统的物理有机化学研究工作,致力探索和揭示氟(氟烷基)转移试剂的结构-活性关系,反应机理以及氟化学独特反应性的科学本质与规律。已在Acc. Chem. Res.J. Am. Chem. Soc.Angew. Chem. Int. Ed.Nat. Commun.等学术期刊发表论文70余篇,论文总被引1800余次,h-index 23

 

代表性论文(5)

1.       Establishing for Cation and Radical Donor Ability Scales of Electrophilic F, CF3, and SCF3 Transfer Reagents, M. Li, X.-S. Xue*, J.-P. Cheng. Acc. Chem. Res.202053, 182.

2.       Radical-Mediated C-C Cleavage of Unstrained Cycloketones and DFT Study for Unusual Regioselectivity, M. Wang, M. Li, S. Yang, X.-S. Xue*, X. Wu, C. Zhu*.Nat. Commun.202011, 672.

3.       Mechanism and Origins of Enantioselectivities in Spirobiindane-based Hypervalent Iodine(III) Induced Asymmetric Dearomatizing Spirolactonizations, H. Zheng, Y. Sang, K. N. Houk*, X.-S. Xue*, J.-P. Cheng. J. Am. Chem. Soc.2019.141, 16046.

4.       Mechanism and Origins of Chemo- and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of β-Substituted Styrenes, B. Zhou, M. K. Haj, E. N. Jacobsen, K. N. Houk,* X.-S. Xue*. J. Am. Chem. Soc.2018,140, 15206.

5.       Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents, J. Zhang, J.-D. Yang, H. Zheng, X.-S. Xue*, H. Mayr*, J.-P. Cheng.Angew. Chem. Int. Ed. 201857, 12690.